Distribution of equilibrium free energies in a thermodynamic system with broken ergodicity

Abstract

At low temperatures the configurational phase space of a macroscopic complex system (e.g., a spin-glass) of $N\sim 10^{23}$ interacting particles may split into an exponential number $\Omega_s \sim \exp({\rm const} \times N)$ of ergodic sub-spaces (thermodynamic states). Previous theoretical studies assumed that the equilibrium collective behavior of such a system is determined by its ground thermodynamic states of the minimal free-energy density, and that the equilibrium free energies follow the distribution of exponential decay. Here we show that these assumptions are not necessarily valid. For some complex systems, the equilibrium free-energy values may follow a Gaussian distribution within an intermediate temperature range, and consequently their equilibrium properties are contributed by {\em excited} thermodynamic states. This work will help improving our understanding of the equilibrium statistical mechanics of spin-glasses and other complex systems.