Anisotropy in magnetic and transport properties of Fe1-xCoxSb2

Abstract

Anisotropic magnetic and electronic transport measurements were carried out on large single crystals of Fe1-xCoxSb2 (0<= x <=1). The semiconducting state of FeSb2 evolves into metallic and weakly ferromagnetic by substitution of Fe with Co for x<0.5. Further doping induces structural transformation from orthorhombic Pnnm structure of FeSb2 to monoclinic P21/c structure of CoSb2 where semiconducting and diamagnetic ground state is restored again. Large magnetoresistance and anisotropy in electronic transport were observed.