Photo-induced separation of chiral isomers in a classical buffer gas

Abstract

We develop a theory of photo-induced drift of chiral molecules or small particles in classical buffer gases. In the absence of a magnetic field there exists a flux of chiral molecules, provided the electromagnetic field is circularly polarized. It has opposite signs for different chiral isomers. In the presence of a magnetic field the flux can be also induced by a linearly polarized (or unpolarized) electromagnetic field. The magnitude of the flux is not proportional to either linear or orbital momentum of the electromagnetic field.