Hopping charge transport in disordered organic materials: where is the disorder?

Abstract

Effect of energetic disorder on charge carrier transport in organic materials has been reexamined. A reliable method for mobility calculation and subsequent evaluation of relevant disorder parameters has been discussed. This method is well suited for a direct calculation of the magnitude of dipolar disorder σdip in polar organic materials from the current transients. Calculation of σdip for several transport materials with varying concentration of polar dopants gives concentration dependences that are in reasonable agreement with theoretical predictions. A possible solution of the puzzle concerning the disorder effect on the mobility temperature dependence has been suggested.

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