Anomalous non-linear response of glassy liquids: general arguments and a Mode-Coupling approach
Abstract
We study theoretically the non-linear response properties of glass formers. We establish several general results which, together with the assumption of Time-Temperature Superposition, lead to a relation between the non-linear response and the derivative of the linear response with respect to temperature. Using results from Mode-Coupling Theory (MCT) and scaling arguments valid close to the glass transition, we obtain the frequency and temperature dependence of the non-linear response in the α and β-regimes. Our results demonstrate that supercooled liquids are characterized by responses to external perturbations that become increasingly non-linear as the glass transition is approached. These results are extended to the case of inhomogeneous perturbing fields.