Staging model of the ordered stacking of vacancy layers and phase separation in the layered NaCoO(x > 0.71) single crystals
Abstract
Phase diagram of NaxCoO2 (x 0.71) has been reinvestigated using electrochemically fine tuned single crystals. Both phase separation and staging phenomena as a result of sodium multi-vacancy cluster ordering have been found. Phase separation phenomenon is observed in the narrow ranges of 0.76 x 0.82 and 0.83 x 0.86. While x = 0.820 shows A-type antiferromagnetic (A-AF) ordering below 22K, x = 0.833 is confirmed to have a magnetic ground state of A-AF ordering below 8K and is only reachable through slow cooling. In addition, x = 0.859 is found to be responsible for the highest A-AF transition temperature at about 29K. Staging model based on ordered stacking of multi-vacancy layers is proposed to explain the hysteretic behavior and A-AF correlation length for x 0.82-0.86.