Glass-like Thermal-Transport in Symmetry-Broken Clathrates

Abstract

We present the quantitative interpretation for the glass-like behavior of thermal conductivities $\kappa(T)$ for type-I clathrate compounds involving off-centered guest ions. It is shown that the dipole-dipole interaction generated in cage/guest-ion systems is crucial to reproduce the characteristics of thermal conductivities for these symmetry-broken clathrates. The above scenario also explains well the difference of $\kappa(T)$ between the $p$-type and the $n$-type $\beta$-BGS found recently by K. Suekuni et al. [Phys. Rev. B, 77 (2008) 235119.]