Quantum effects in a weakly-frustrated S=1/2 two-dimensional Heisenberg antiferromagnet in an applied magnetic field

Abstract

We have studied the two-dimensional S=1/2 square-lattice antiferromagnet Cu(pz)2(ClO4)2 using inelastic neutron scattering and series expansion calculations. We show that the presence of antiferromagnetic next-nearest neighbor interactions enhances quantum fluctuations associated with resonating valence bonds. Intermediate magnetic fields lead to a selective tuning of resonating valence bonds and a spectacular inversion of the zone-boundary dispersion, providing novel insight into 2D antiferromagnetism in the quantum limit.

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