Transition frequency shifts with fine-structure constant variation for Yb II

Abstract

In this paper we report calculations of the relativistic corrections to transition frequencies (q factors) of Yb II for the transitions from the odd-parity states to the metastable state $4f^{13}6s^2 ^2F_{7/2}^o$. These transitions are of particular interest experimentally since they possess some of the largest q factors calculated to date and the $^2F_{7/2}^o$ state can be prepared with high efficiency. This makes Yb II a very attractive candidate for the laboratory search for variation of the fine-structure constant alpha.