The B-X and C-X band systems of CuCl revisited: A laser-induced fluorescence study in 465-490 nm

Abstract

We have reinvestigated the B-X and C-X band systems of CuCl by recording the laser-induced fluorescence excitation spectra in 20400-21800 cm^{-1}. The rotational analyses in Hund's case (a) revealed unambiguously a singlet-to-singlet transition nature. The measured lifetimes of a few microseconds seem too long for singlets and too short for triplets, which we think is actually in favor of a picture of singlet ({1}^Pi and {1}^Sigma^{+})-triplet ({3}^Pi_{0,1,2}) mixed states in the B and C band systems of CuCl. The two excited states we observed in our spectra may be the singlets that have been strongly "contaminated" by their triplet neighbors.