Method for Creating and Detecting Hydrogen Sorption Sites Using Gamma Radiation

Abstract

Using gamma radiation and volumetric analysis of desorbed gas, hydrogen gas bonding sites have been created and detected in select materials. Desorption of hydrogen was followed over a benign temperature-pressure range. The extent of active site formation depends on radiation dosage; quenching of sites occurs over prolonged heating at low pressures. An estimate of the hydrogen bonding energy can be made on the basis of a partial temperature profile of the gas released at one atmosphere pressure. It appears that the bonding energy can be adjusted by mixing candidate materials. A guide for further investigation and application of the method is outlined.