Ideal chains with fixed self-intersection rate

Abstract

We consider ideal chains in a hypercubic lattice Zd, d≥3, with a fixed ratio m of self-intersection per monomer. Despite the simplicity of the geometrical constraint, this model shows some interesting properties, such as a collapse transition for a critical value mc. Numerical simulations show a Self-Avoiding-Walk-like behavior for m<mc, and a compact cluster configuration for m>mc. The collapse seems to show the same characteristics as the canonical thermodynamical models for the coil-globule transition.

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