Internal and External Fluctuation Activated Non-equilibrium Reactive Rate Process

Abstract

The activated rate process for non-equilibrium open systems is studied taking into account both internal and external noise fluctuations in a unified way. The probability of a particle diffusing passing over the saddle point and the rate constant together with the effective transmission coefficient are calculated via the method of reactive flux. We find that the complexity of internal noise is always harmful to the diffusion of particles. However the external modulation may be beneficial to the rate process.