Dimensionality controlled Mott transition and correlation effects in single- and bi-layer perovskite iridates

Abstract

We studied Sr2IrO4 and Sr3Ir2O7 using angle-resolved photoemission spectroscopy (ARPES), making direct experimental determinations of intra- and inter-cell coupling parameters as well as Mott correlations and gap sizes. The results are generally consistent with LDA+U+Spin-orbit coupling (SOC) calculations, though the calculations missed the momentum positions of the dominant electronic states and neglected the importance of inter-cell coupling on the size of the Mott gap. The calculations also ignore the correlation-induced spectral peak widths, which are critical for making a connection to activation energies determined from transport experiments. The data indicate a dimensionality-controlled Mott transition in these 5d transition-metal oxides (TMOs).