How entropy and hydrodynamics cooperate in rectifying particle transport

Abstract

Using the analytical Fick-Jacobs approximation formalism and extensive Brownian dynamics simulations we study particle transport through two-dimensional periodic channels with triangularly shaped walls. Directed motion is caused by the interplay of constant bias acting along the channel axis and a pressure-driven flow. In particular, we analyze the particle mobility and the effective diffusion coefficient. The mechanisms of entropic rectification is revealed in channels with a broken spatial reflection symmetry in presence of hydrodynamically enforced entropic trapping. Due to the combined action of the forcing and the pressure-driven flow field, efficient rectification with a drastically reduced diffusivity is achieved.