Dissociative electron attachment to carbon dioxide via the 2u shape resonance

Abstract

Momentum imaging measurements from two experiments are presented and interpreted with the aid of new ab initio theoretical calculations to describe the dissociative electron attachment (DEA) dynamics. We address the problem of how the 4 eV 2u shape resonance in CO2 proceeds to dissociate to CO(1+) + O-(2P) by DEA.

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