Electronic phase diagram in the new BiS2-based Sr1-xLaxFBiS2 system

Abstract

In this paper, we systematically study the electron doping effect in a new BiS2-based system Sr1-xLaxFBiS2(0<x<0.7) through multiple techniques of X-ray diffraction, electrical transport, magnetic susceptibility, and Hall effect measurements. The parent compound SrFBiS2 is found to possess a semiconducting-like ground state, with thermally activation energy Eg=38 meV. By the partial substitution of La for Sr, superconductivity emerges when x > 0.3, reaching its maximal superconducting transition temperature Tc=3.5 K at x=0.55. In the normal state of superconducting samples, it is clearly seen that there exists a crossover from metallic to semiconducting state below a temperature Tmin, which shifts to lower temperatures with increasing La content. Based on these measurements, the associated electronic phase diagram of Sr1-xLaxFBiS2 system has thus been established.