Combinatorial model for the ferroelectric domain-network formation in hexagonal manganites

Abstract

As the result of the high-temperature improper ferroelectric transition occurring in YMnO3 and other hexagonal manganites a striking domain pattern was observed: an emergence of six domains of alternating polarization from one point in a vortex-like pattern. We derive the formation and distribution of the domain-vortex network from a combinatorial analysis based on order-parameter symmetry and lattice geometry. The analysis leads to stable vortex-like configurations of the six domain states in the basal plane perpendicular to the polarization and to fragmented vortices in planes parallel to the polarization. The predictions are debated in the light of existing experimental and theoretical work on the vortex domain state. The relation of the symmetry-determined geomet- rical defects to the topological defects proposed to describe the behavior of YMnO3 near the Curie temperature is discussed.