Structural and optical properties of cobalt slanted columnar thin films conformally coated with graphene by chemical vapor deposition

Abstract

A slanted cobalt sculptured columnar thin film was fabricated using glancing angle deposition, and coated subsequently with graphene using a low temperature chemical vapor deposition process. The graphene deposition process preserves shape and geometry of the sculptured thin film, which was confirmed by scanning electron microscopy. According to the Raman spectroscopy results, the graphene coating is two to three monolayers thick and has a high defect concentration. The graphene coverage within the sculptured thin film is determined from generalized spectroscopic ellipsometry using a generalized anisotropic Bruggeman effective medium approximation. The graphene coverage as well as structural parameters of the thin film agree excellently with electron microscopy and Raman observations, and suggest that the graphene coating is conformal.