Functionalization of Single-Wall Carbon Nanotubes with Chromophores of Opposite Internal Dipole Orientation

Abstract

We report the functionalization of carbon nanotubes with two azobenzene-based chromophores with large internal dipole moments and opposite dipole orientations. The molecules are attached to the nanotubes non-covalently via a pyrene tether. A combination of characterization techniques shows uniform molecular coverage on the nanotubes, with minimal aggregation of excess chromophores on the substrate. The large on/off ratios and the sub-threshold swings of the nanotube-based field-effect transistors (FETs) are preserved after functionalization, and different shifts in threshold voltage are observed for each chromophore. Ab initio calculations verify the properties of the synthesized chromophores and indicate very small charge transfer, confirming a strong, non-covalent functionalization.