Growth by SR method and characterization of bis(thiourea)zinc(II) chloride single crystals

Abstract

Large size single crystals of bis(thiourea)zinc(II) chloride (BTZC), a potential nonlinear optical material, have been grown successfully by the Sankaranarayanan Ramasamy (SR) method. Powder X-ray diffraction and Fourier transform infrared analyses confirmed the material of the grown crystal. Thermal stability was assessed by the thermogravimetric differential thermal analysis. The high-resolution X-ray diffraction and dielectric measurements indicate that the crystal grown by the SR method has good crystalline perfection and low density of defects.