Non-canonical statistics of finite quantum system

Abstract

The canonical statistics describes the statistical properties of an open system by assuming its coupling with the heat bath infinitesimal in comparison with the total energy in thermodynamic limit. In this paper, we generally derive a non-canonical distribution for the open system with a finite coupling to the heat bath, which deforms the energy shell to effectively modify the conventional canonical way. The obtained non-canonical distribution reflects the back action of system on the bath, and thus depicts the statistical correlations through energy fluctuations.