Low energy nuclear reactions driven by discrete breathers

Abstract

A new mechanism of LENR in solids is proposed, which is based on the large amplitude anharmonic lattice vibrations, a.k.a. intrinsic localized modes or discrete breathers (DBs). In particular, so called gap DBs, which can arise in diatomic crystals such as metal hydrides, are argued to be the LENR catalyzers. The large mass difference between H or D and the metal atoms provides a gap in phonon spectrum, in which DBs can be excited in the H/D sub-lattice resulting in extreme dynamic closing of adjacent H/D atoms (~ 0.01 {\AA}) required for the tunneling through nuclear Coulomb barrier. DBs have been shown to arise either via thermal activation at elevated temperatures or via knocking atoms out of equilibrium positions under non-equilibrium gas loading conditions, employed under radiolysis or plasma deposition methods. The DB statistics in both cases is analyzed, and an attempt is made to quantify part of the vibrational problem in terms of electrochemical current or ion flux, connecting them with external excitation of DBs that act as nano-colliders of deuterons triggering LENR. Resulting analytical expressions (under selected set of material parameters) describe quantitatively the observed exponential dependence on temperature and linear dependence on the electric (or ion) current. Possible ways of engineering the nuclear active environment based on the present concept are discussed.