The Limit of Mechanical Stability in Quantum Crystals: A Diffusion Monte Carlo Study of Solid 4He

Abstract

We present a first-principles study of the energy and elastic properties of solid helium at pressures below the range in which is energetically stable. We find that the limit of mechanical stability in hcp 4He is $P_{s}$ = -33.82 bar, which lies significantly below the spinodal pressure found in the liquid phase (i.e., -9.6 bar). Furthermore, we show that the pressure variation of the transverse and longitudinal sound velocities close to $P_{s}$ do not follow a power law of the form $\propto \left( P - P_{s} \right)^{\gamma}$, in contrast to what is observed on the fluid.