Enhancement of Superconductivity in La$_{1-x}$Sm$_{x}$O$_{0.5}$F$_{0.5}$BiS$_2$

Abstract

The superconducting and normal-state properties of La$_{1-x}$Sm$_{x}$O$_{0.5}$F$_{0.5}$BiS$_{2}$ (0.1 $\leqslant$ $x$ $\leqslant$ 0.9) have been studied via electrical resistivity, magnetic susceptibility, and specific heat measurements. By using suitable synthesis conditions, Sm exhibits considerable solubility into the CeOBiS$_{2}$-type LaO$_{0.5}$F$_{0.5}$BiS$_{2}$ lattice. In addition to a considerable enhancement of the superconducting volume fraction, it is found that the superconducting transition temperature $T_{c}$ is dramatically enhanced with increasing Sm concentration to 5.4 K at $x$ = 0.8. These results suggest that $T_{c}$ for SmO$_{0.5}$F$_{0.5}$BiS$_{2}$ could be as high as $\sim$6.2 K and comparably high $T_{c}$ values might also be obtained in $Ln$O$_{0.5}$F$_{0.5}$BiS$_{2}$ ($Ln$ = Eu - Tm) if these compounds can be synthesized.