Thermodynamic and dynamic dielectric properties of one-dimensional hydrogen bonded ferroelectric of PbHPO$_4$-type

Abstract

Within the modified model of proton ordering of one-dimensional ferroelectric having hydrogen bonds of PbHPO$_4$-type, their thermodynamic and dynamic characteristics are studied and calculated taking into account the linear (by crystal deformations $\varepsilon_i$ ($i=1,3$) and $\varepsilon_4$) contributions into the energy of a proton system but without taking into account the tunneling in the two-particle cluster approximation. There has been obtained a good quantitative description of the temperature dependence of polarization, static dielectric permittivity, heat capacity and frequency dependence of dynamic dielectric permittivity at different temperatures for PbHPO$_4$ and PbHDO$_4$ crystals.