Quasirelativistic calculation of 4s24p5, 4s24p44d and 4s4p6 configuration spectroscopic parameters for the W39+ ion

Abstract

The ab initio quasirelativistic Hartree-Fock method developed specifically for the calculation of spectral parameters of heavy atoms and highly charged ions is used to derive spectral data for the 4s24p5, 4s24p44d and 4s4p6 configurations of the multicharged tungsten ion W39+. The relativistic effects are taken into account in the Breit-Pauli approximation for the quasirelativistic Hartree-Fock radial orbitals. The configuration interaction method is applied to include the electron correlation effects. Produced data are compared with existing experimental measurements and theoretical calculations.

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