Multiple magnetic transitions in the spin-$\frac12$ chain antiferromagnet SrCuTe2O6

Abstract

Using thermodynamic measurements and density-functional band-structure calculations, we explore magnetic behavior of SrCuTe2O6. Despite being a structural sibling of a three-dimensional frustrated system PbCuTe2O6, this spin-1/2 quantum magnet shows remarkably different low-temperature behavior. Above 7 K, magnetic susceptibility of SrCuTe2O6 follows the spin-chain model with the antiferromagnetic intrachain coupling of J = 49.3 K. We ascribe this quasi-one-dimensional behavior to the leading third-neighbor coupling that involves a weakly bent Cu--O......O--Cu superexchange pathway with a short O.....O contact of 2.79 \AA. Below 5 K, SrCuTe2O6 undergoes two consecutive magnetic transitions that may be triggered by the frustrated nature of interchain couplings. Field dependence of the magnetic transitions (phase diagram) is reported.