Universal threshold law for ion-neutral-neutral three-body recombination
Abstract
A very recently method for classical trajectory calculations for three-body collision [J. P\'erez-R\'ios, S. Ragole, J. Wang and C. H. Greene, J. Chem. Phys. 140, 044307 (2014)] has been applied to describe ion-neutral-neutral ternary processes for low energy collisions: 0.1 mK - 10 mK. As a result, a threshold law for the three-body recombination cross section is obtained and corroborated both, experimentally and numerically. The derived threshold law predicts the formation of weakly bound dimers, with binding energies comparable to the collision energy of the collisional partners. In this low energy range, this analysis predicts that molecular ions should dominate over molecular neutrals as the most products formed.
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