Dependence of the Energy Transfer to Graphene on the Excitation Energy

Abstract

Fluorescence studies of natural photosynthetic complexes on a graphene layer demonstrate pronounced influence of the excitation wavelength on the energy transfer efficiency to graphene. Ultraviolet light yields much faster decay of fluorescence, with average efficiencies of the energy transfer equal to 87% and 65% for excitation at 405 nm and 640 nm, respectively. This implies that focused light changes locally the properties of graphene affecting the energy transfer dynamics, in an analogous way as in the case of metallic nanostructures. Demonstrating optical control of the energy transfer is important for exploiting unique properties of graphene in photonic and sensing architectures.