Thermodynamics and the Structure of Quantum Theory as a Generalized Probabilistic Theory

Abstract

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized Probabilistic Theories". For these theories, a thought experiment by von Neumann is adapted to obtain a natural thermodynamic entropy definition, following a proposal by J. Barrett. Mathematical properties of this entropy are compared to physical consequences of the thought experiment. The validity of the second law of thermodynamics is investigated. In that context, observables and projective measurements are generalized to prove an entropy increase for projective measurements of ensembles. Information-theoretically motivated definitions of the entropy are compared to the entropy from the thermodynamic thought experiment. The conditions for the thermodynamic entropy to be well-defined are considered in greater detail. Several further properties of the theories under consideration (e.g. whether there is higher order interference, Pfister's state discrimination principle) and their relation to entropy are investigated.