Influence of in-plane and bridging oxygen vacancies of SnO2 nanostructures on CH4 sensing at low operating temperatures
Abstract
Role of 'O' defects in sensing pollutant with nanostructured SnO2 is not well understood, especially at low temperatures. SnO2 nanoparticles were grown by soft chemistry route followed by subsequent annealing treatment under specific conditions. Nanowires were grown by chemical vapor deposition technique. A systematic photoluminescence (PL) investigation of 'O' defects in SnO2 nanostructures revealed a strong correlation between shallow donors created by the in-plane and the bridging 'O' vacancies and gas sensing at low temperatures. These SnO2 nanostructures detected methane (CH4), a reducing and green house gas at a low temperature of 50 oC. Response of CH4 was found to be strongly dependent on surface defect in comparison to surface to volume ratio. Control over 'O' vacancies during the synthesis of SnO2 nanomaterials, as supported by X-ray photoelectron spectroscopy and subsequent elucidation for low temperature sensing are demonstrated.
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