Clues on chemical mechanisms from renormalizability: The example of a noisy cubic autocatalytic model

Abstract

We study the effect of noise on the renormalizability of a specific reaction-diffusion system of equations describing a cubic autocatalytic chemical reaction. The noise we are using is gaussian with power-law correlations in space, characterized by an amplitude A and a noise exponent y. We show that changing the noise exponent is equivalent to the substitution ds → d eff = ds - y and thus modifies the divergence structure of loop integrals (ds is the dimension of space). The model is renormalizable at one-loop for d eff < 6 and nonrenormalizable for d eff ≥ 6. The effects of noise-generated higher order interactions are discussed. In particular, we show how noise induces new interaction terms that can be interpreted as a manifestation of some (internal) "chemical mechanism". We also show how ideas of effective field theory can be applied to construct a more fundamental chemical model for this system.

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