On mechanism of high-temperature superconductivity in hydrogen sulfide at 200 GPa: transition into superconducting anti-adiabatic state in coupling to H-vibrations

Abstract

We have shown that adiabatic electronic structure of superconducting phase of sulphur hydride at 200 GPa is unstable toward vibration motion of H-atoms. Theoretical study indicates that in coupling to H-vibrations, system undergoes transition from adiabatic into stabilised anti-adiabatic multi-gap superconducting state at temperature which can reach 203 K.