Stark effect spectroscopy of mono- and few-layer MoS2

Abstract

We demonstrate electrical control of the A-exciton interband transition in mono- and few-layer MoS2 crystals embedded into photocapacitor devices via the DC Stark effect. Electric field dependent low-temperature photoluminescence spectroscopy reveals a significant tuneability of the A-exciton transition energy, up to 16 meV, from which we extract the mean DC exciton polarisability <β>N = (0.58 0.25) · 10-8 DmV-1. The exciton polarisability is shown to be layer-independent, indicating a strong localisation of both electron and hole wave functions in each individual layer.

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