Eyring equation and the second order rate law: Overcoming a paradox
Abstract
The standard transition state theory (TST) of bimolecular reactions was recently shown to lead to a rate law in disagreement with the expected second order rate law [Bonnet L., Rayez J.-C. Int. J. Quantum Chem. 2010, 110, 2355]. An alternative derivation was proposed which allows to overcome this paradox. This derivation allows to get at the same time the good rate law and Eyring equation for the rate constant. The purpose of this paper is to provide rigorous and convincing theoretical arguments in order to strengthen these developments and improve their visibility.
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