The giant frequency shift of intramolecular O-H vibration band in the raman spectra of water on the silver surface

Abstract

The giant frequency shift was observed in Raman spectra for inramolecular O-H vibration band. The effect was observed in SERS-condition experiment, when exciting light was focused by short-focus objective on the Ag-surface, merged in water. The shift was detected relatively to the regularl position of band, measured from the bulk of water under the same other conditions.

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