Magnus expansions and pseudospectra of Master Equations

Abstract

New directions in research on master equations are showcased by example. Magnus expansions, time-varying rates, and pseudospectra are highlighted. Exact eigenvalues are found and contrasted with the large errors produced by standard numerical methods in some cases. Isomerisation provides a running example and an illustrative application to chemical kinetics. We also give a brief example of the totally asymmetric exclusion process.