Determination of the nature of fluctuations using 8Li and 9Li β-NMR and spin-lattice relaxation

Abstract

We report a comparison of the 1/T1 spin lattice relaxation rates (SLR) for 9Li and 8Li in Pt and SrTiO3, in order to differentiate between magnetic and electric quadrupolar relaxation mechanisms. In Pt, the ratio of the 1/T1 spin relaxation rates RPt was found to be 6.82(29), which is close to but less than the theoretical limit of 7.68 for pure magnetic relaxation. In SrTiO3 this ratio was found to be 2.7(3), which is close but larger than the theoretical limit of 2.14 expected for pure electric quadrupolar relaxation. These results bring new insight into the nature of the fluctuations in the local environment of implanted 8Li observed by β-NMR.

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