Thermally Activated Motion of Sodium Cations in Insulating Parent Low-Silica X Zeolite
Abstract
We report a 23Na spin-lattice relaxation rate, T1-1, in low-silica X zeolite. T1-1 follows multiple BPP-type behavior as a result of thermal motion of sodium cations in insulating material. The estimated lowest activation energy of 15~meV is much lower than 100~meV observed previously for sodium motion in heavily Na-loaded samples and is most likely attributed to short-distance jumps of sodium cations between sites within the same supercage.
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