Theoretical overview of black phosphorus

Abstract

We review the basic optical, electronic, optoelectronic, thermoelectric and mechanical properties of few-layer black phosphorus (BP), a layered semiconductor that can be exfoliated from bulk BP, the most stable allotrope of phosphorus. The distinguishing trait of BP is its highly anisotropic crystal structure, which leads to strong optical linear dichroism, elliptical plasmonics energy surfaces, anisotropic electronic and thermal conductivities and elasticity. We provide tutorial-like discussion of these phenomena and their theoretical models.