Acoustic Graphene Plasmon Nanoresonators for Field Enhanced Infrared Molecular Spectroscopy

Abstract

Field-enhanced infrared molecular spectroscopy has been widely applied in chemical analysis, environment monitoring, and food and drug safety. The sensitivity of molecular spectroscopy critically depends on the electromagnetic field confinement and enhancement in the sensing elements. Here we propose a concept for sensing, consisting of a graphene plasmonic nanoresonator separated from a metallic film by a nanometric spacer. Such a resonator can support acoustic graphene plasmons, AGPs; that provide ultra-confined electromagnetic fields and strong field enhancement. Compared to conventional plasmons in graphene, AGPs exhibit a much higher spontaneous emission rate, higher sensitivity to the dielectric permittivity inside the AGP nano resonator, and remarkable capability to enhance molecular vibrational fingerprints, of nanoscale analyte samples. Our work opens novel avenues for sensing of ultra-small volume of molecules, as well as for studying enhanced light-matter interaction, e.g. strong coupling applications.