Influence of P2O5 and SiO2 addition on the phase, microstructure, and electrical properties of KNbO3

Abstract

In this contribution, the effect of P2O5 and SiO2 addition on the phase, microstructure, and electrical properties of KNbO3 was studied. Sample powders with the general formula (1-x)KNbO3.xP2O5 (x = 0.03, 0.05) and (1-x)KNbO3.xSiO2 (x = 0.1) were prepared via mixed-oxide route. The thermal behavior of the mixed-milled powder was investigated by TG/DTA which revealed an overall weight loss of 33.4 wt % in the temperature range of 30 < T < 1200 C and crystallization exotherm occurring at about 795 C. The present results indicated that P2O5 acted as a sintering aid and lowered the sintering temperature by about 30 C and promoted densification of KNbO3. Sample compositions at various stages of processing were characterized using X-ray diffraction. Samples sintered at T < 1020 C revealed mainly KNbO3 together with a couple of low-intensity K3NbO4 peaks as a secondary phase. The SEM images of (1-x)KNbO3.xSiO2 (x = 0.1) samples showed a slight increase in the average grain size from 3.76 um to 3.86 um with an increase in sintering temperature from 1000 C to 1020 C. Strong variations in dielectric constant and loss tangent were observed due to P2O5 and SiO2 addition as well as frequency of the applied AC signals.