Solution of the time dependent Schr\"odinger equation leading to Fowler-Nordheim field emission

Abstract

We solve the time-dependent Schr\"odinger equation describing the emission of electrons from a metal surface by an external electric field $E$, turned on at $t=0$. Starting with a wave function $\psi(x,0)$, representing a generalized eigenfunction when $E=0$, we find $\psi(x,t)$ and show that it approaches, as $t\to\infty$, the Fowler-Nordheim tunneling wavefunction $\psi_E$. The deviation of $\psi$ from $\psi_E$ decays asymptotically as a power law $t^{-\frac32}$. The time scales involved for typical metals and fields of several V/nm are of the order of femtoseconds.