Normal-state properties of the antiperovskite oxide Sr3-xSnO revealed by 119Sn-NMR

Abstract

We have performed 119Sn-NMR measurements on the antiperovskite oxide superconductor Sr3-xSnO to investigate how its normal state changes with the Sr deficiency. A two-peak structure was observed in the NMR spectra of all the measured samples. This suggests that the phase separation tends to occur between the nearly stoichiometric and heavily Sr-deficient Sr3-xSnO phases. The measurement of the nuclear spin-lattice relaxation rate 1/T1 indicates that the Sr-deficient phase shows a conventional metallic behavior due to the heavy hole doping. In contrast, the nearly stoichiometric phase exhibits unusual temperature dependence of 1/T1, attributable to the presence of a Dirac-electron band.

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