Shear induced phase separation of Wormlike micelles-nanoparticle system : formation of a long-range ordered nanoparticle structure

Abstract

Shearing of nanocomposites has shown to produce ordered nanostructures and orientation in the polymeric matrix. Due to the importance of the formation of an ordered structure of nanoparticles in a polymeric matrix to device wearable, flexible and photonic materials, its useful to get an insight of the shear-induced ordering and other properties of the polymeric nanocomposites. In this paper, we use a model Wormlike micellar matrix to study the arrangement and morphology of nanoparticles in the composite when the system is sheared using a hybrid multiparticle dynamics and molecular dynamics simulation technique. We observe a shear-induced phase separation of nanoparticles as well as an increase in the long-range ordering of the nanostructures as a result of shear. We also show that in order to form a well-packed and highly ordered structure, the nanoparticles with a smaller size should be preferred.