Transferability of crystal-field parameters for rare-earth ions in Y2SiO5 tested by Zeeman spectroscopy
Abstract
Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two C1 point-group sites in Er3+:Y2SiO5 may be transferred to other ions. The two crystallographic six- and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.
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