Marangoni flow in freely suspended liquid films

Abstract

We demonstrate controlled material transport driven by temperature gradients in thin freely suspended smectic films. The films with submicrometer thicknesses and lateral extensions of several millimeters were studied in microgravity during suborbital rocket flights. In-plane temperature gradients cause two specific Marangoni effects, directed flow and convection patterns. At low gradients, practically thresholdless, flow transports material with a normal (negative) temperature coefficient of the surface tension, $d\sigma/dT<0$, from the hot to the cold film edge. That material accumulates at the cold film border. In materials with positive temperature coefficient, $d\sigma/dT>0$, the reverse transport from the cold to the hot edge is observed. We present a model that describes the effect quantitatively.