Interpretation of saddle-splay and the Oseen-Frank free energy in liquid crystals

Abstract

This article re-examines a classic question in liquid-crystal physics: What are the elastic modes of a nematic liquid crystal? The analysis uses a recent mathematical construction, which breaks the director gradient tensor into four distinct types of mathematical objects, representing splay, twist, bend, and a fourth deformation mode. With this construction, the Oseen-Frank free energy can be written as the sum of squares of the four modes, and saddle-splay can be regarded as bulk rather than surface elasticity. This interpretation leads to an alternative way to think about several previous results in liquid-crystal physics, including: (1) free energy balance between cholesteric and blue phases, (2) director deformations in hybrid-aligned-nematic cells, (3) spontaneous twist of achiral liquid crystals confined in a torus or cylinder, and (4) curvature of smectic layers.