Tightly bound excitons in two-dimensional semiconductors with a flat valence band

Abstract

This theoretical paper offers an explicit expression for the binding energy of excitons in a two-dimensional semiconductor with a flat valence band. The formula has been derived quasiclassically assuming that the exciton is tightly bound; i.e., its ground-state radius is determined by the intrinsic polarizability of the semiconductor rather than by the dielectric properties of the environment. The model is relevant to a few two-dimensional semiconductors discovered recently, including distorted 1T-TiSe$_2$, with a supposedly unstable electronic ground state. The valence band flatness reduces the exciton binding energy, which also may have an effect on the phase transition to an excitonic insulator.